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ChemicalBook >> CAS DataBase List >>(S)-(-)-2-Methyl-1-butanol

(S)-(-)-2-Methyl-1-butanol

CAS No.
1565-80-6
Chemical Name:
(S)-(-)-2-Methyl-1-butanol
Synonyms
AMYL ALCOHOL;N-PENTANOL;FUSEL OIL;N-PENTYL ALCOHOL;AMYL ALCOHOL, N-;FEMA 2056;ALCOHOL C5;L-pentanol;(s)-1-butano;BUTYLCARBINOL
CBNumber:
CB7853148
Molecular Formula:
C5H12O
Molecular Weight:
88.15
MDL Number:
MFCD00064299
MOL File:
1565-80-6.mol
MSDS File:
SDS
Last updated:2024-11-28 16:31:43

(S)-(-)-2-Methyl-1-butanol Properties

Melting point -70 °C
alpha -5.8 º (neat 23 ºC)
Boiling point 136-138 °C(lit.)
Density 0.811 g/mL at 25 °C(lit.)
vapor density 3 (vs air)
vapor pressure 1 mm Hg ( 13.6 °C)
refractive index n20/D 1.409(lit.)
Flash point 120 °F
storage temp. 2-8°C
solubility soluble in Chloroform, Ethanol
pka 15.24±0.10(Predicted)
form clear liquid
color Colorless to Almost colorless
Odor ethereal fresh
optical activity [α]23/D 5.8°, neat
Water Solubility 36 g/L (30 ºC)
Merck 14,6030
BRN 1718809
Dielectric constant 15.8(20℃)
LogP 1.223 (est)
CAS DataBase Reference 1565-80-6(CAS DataBase Reference)
FDA UNII
NIST Chemistry Reference
EPA Substance Registry System

SAFETY

Risk and Safety Statements

Symbol(GHS)  trực tiếp đá gà hôm nayLiên kết đăng nhậptrực tiếp đá gà hôm nayLiên kết đăng nhập
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H332-H335
Precautionary statements  P210-P304+P340+P312
Hazard Codes  Xn
Risk Statements  10-20-37-66-2017/10/20
Safety Statements  46-24/25
RIDADR  UN 1105 3/PG 3
WGK Germany  1
RTECS  SB9800000
HazardClass  3
PackingGroup  III
HS Code  29051990
NFPA 704
2
1 0

(S)-(-)-2-Methyl-1-butanol price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 65980 (S)-(?)-2-Methylbutanol ≥95.0% (sum of enantiomers, GC) 1565-80-6 100ml $96.9 2025-03-01 Buy
Sigma-Aldrich 65980 (S)-(?)-2-Methylbutanol ≥95.0% (sum of enantiomers, GC) 1565-80-6 500ml $164.8 2025-03-01 Buy
TCI Chemical M0170 (S)-(-)-2-Methyl-1-butanol >98.0%(GC) 1565-80-6 25mL $98 2025-03-01 Buy
Sigma-Aldrich A83407 (S)-(?)-2-Methylbutanol 99% 1565-80-6 10g $119 2025-03-01 Buy
TRC M295215 (S)-(-)-2-Methylbutanol 1565-80-6 5g $55 2022-12-16 Buy
Product number Packaging Price Buy
65980 100ml $96.9 Buy
65980 500ml $164.8 Buy
M0170 25mL $98 Buy
A83407 10g $119 Buy
M295215 5g $55 Buy

(S)-(-)-2-Methyl-1-butanol Chemical Properties,Uses,Production

Chemical Properties

clear colourless liquid

Uses

(S)-(?)-2-Methylbutanol can be used to prepare:

  • (S)-(?)-2-Methyl-1-butyloxy carbonyl amino hexyl isocyanate (MBI), which is used to synthesize isocyanate copolymers.
  • Chiral alkoxynaphathoic acid derivatives having liquid crystalline properties.
  • 3,4-Bis[(S)-2-methylbutoxy]thiophene, a key intermediate for the synthesis of polythiophenes.

Uses

(S)-(-)-2-Methylbutanol can be used as a reactant to prepare:

  • Methylbutyl-2-(3-thienyl)acetate (MBTA) by esterification reaction with 3-thiophene acetic acid in the presence of an acid catalyst.
  • (2S)-2-Methyl-1-butanesulfenyl chloride by reacting with thioacetic acid using Mitsunobu reaction conditions.
  • (+)-Violapyrone C and (-)-myxalamide A.

Definition

ChEBI: The (S)-enantiomer of 2-methylbutan-1-ol.

General Description

rest mainly 3-methyl-1-butanol

Purification Methods

Reflux the butanol with CaO, distil, reflux with magnesium and again fractionally distil it. A small sample of highly purified material is obtained by fractional crystallisation after conversion into a suitable ester such as the trinitrophthalate or the 3-nitrophthalate. The latter is converted to the cinchonine salt in acetone and recrystallised from CHCl3 by adding pentane. The salt is saponified, extracted with ether, and fractionally distilled. [Terry et al. J Chem Eng Data 5 403 1960, Beilstein 1 IV 1666.]
1449306-90-4
1565-80-6
Synthesis of (S)-(-)-2-Methyl-1-butanol from Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy-
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View Lastest Price from (S)-(-)-2-Methyl-1-butanol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
trực tiếp đá gà hôm nayLiên kết đăng nhập 2022-07-02 (S)-(-)-2-Methylbutanol >=95.0% (sum of enantiomers, GC)
1565-80-6
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
trực tiếp đá gà hôm nayLiên kết đăng nhập 2020-12-27 (S)-(-)-2-Methyl-1-butanol
1565-80-6
US $6.60 / KG 1KG 97%-99% 1kg-1000kg Career Henan Chemical Co
(S)-2-Methyl-1-butanol,99%e.e. (S)-(-)-2-Methylbutanol >=95.0% (suM of enantioMers, GC) (S)-(-)-2-Methylbutanol 99% (s)-1-butano (S)-2-methyl-butan-1-ol AMYL ALCOHOL, NORMAL ALCOHOL C5 1-PENTANOL ALCOHOL 1-PENTYL ALCOHOL FEMA 2056 BUTYLCARBINOL PRI-N-AMYL ALCOHOL (S)-(-)-2-Methyl-1-butanol (S)-(-)-2-Methylbutanol (S)-(-)-sec-Butylcarbinol 1-Butanol, 2-methyl-, (2S)- (S)-(-)-2-Methyl-1-butanol, 98+% (S)-(-)-2-Methyl-1-butanol, Active amyl alcohol Active amyl alcohol, Prim. active amyl alcohol (2S)-2-Methyl-1-butanol (2S)-2-Methylbutane-1-ol (S)-(-)-2-Methyl-1-butanol,99% D-2-METHYL-1-BUTANOL, ROT.-4.5 degrees 3-(4-((S)-()-2-Methyl-1-butanol active-Amyl Alcohol sec-Butylcarbinol N-BUTYLCARBINOL WATER STANDARD, AMYL ALCOHOL L-pentanol (S)-(-)-2-Methyl-1-butanol> AMYL ALCOHOL, N- AMYL ALCOHOL FUSEL OIL N-PENTYL ALCOHOL N-PENTANOL 1565-80-6 71410 30899195 Monofunctional Alkanes 1-Alkanols Monofunctional & 伪,蠅-Bifunctional Alkanes Building Blocks Analytical Standards Analytical Chromatography Product Catalog Alcohols Alphabetic Asymmetric Synthesis C2 to C6 ALCOHOL Organic Building Blocks Chiral Resolution Reagents Chiral Resolving Reagents PA - PEN Oxygen Compounds Building Blocks for Liquid Crystals Chiral Building Blocks Chiral Compounds (Building Blocks for Liquid Crystals) Functional Materials Glycidyl Compounds, etc. (Chiral)
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